In
all metallic alloys, certain material specifications are set forth to
accurately classify the particular metal blend in question. stainless steel is
one of the most commonly used metal alloys in the market today, and as such,
many variations have been developed from the base mixture for more specialized
uses. This particular stainless steel 316 standard was designed with extra
additions of chrome for improved corrosion resistance against chlorine. Its
most common uses today are mainly in pharmaceutical and food production
related equipment, but it is also called "marine grade" steel for its uses
in maritime vessel production.Repeatability testing was done on a certified block of 316 stainless steel to determine the precision achievable against the standard reference values on the Rigaku ZSX Primus series of wavelength dispersive X-ray fluorescence Spectrometers. This was done using the convenient "Standardless" Semi-Quantitative (or SQX) software in seven consecutive dynamic analyses set-up in a canned qualitative routine scan named for its ease: EZScan
The standard 316 stainless steel block is shown mounted in a 30 mm sample holder in Image 1. The complied repeatability and statistical data, as well as the standard referenced values for stainless steel 316 product specifications, can be seen in Table 1.
The data in Table 1 shows a high degree of precision with minute Standard Deviation and RSD % values. From these results, the conclusion can be made that this stainless steel 316 metallic alloy can be consistently identified to within product specs, without reliance on a standard calibration, through the Rigaku SQX software on the Rigaku ZSX Primus Series of WD-XRF Spectrometers.
|
SRM |
Primus |
SRM |
Primus |
|
|
Repeatability Stats |
SS 316-Ni |
Ni |
SS 316-Cr |
Cr |
|
Expected |
mass % |
Expected |
mass % |
|
|
SS 316-1 |
10.000-14.000 |
10.170 |
16.000-18.000 |
16.773 |
|
SS 316-2 |
10.000-14.000 |
10.238 |
16.000-18.000 |
16.622 |
|
SS 316-3 |
10.000-14.000 |
10.134 |
16.000-18.000 |
16.629 |
|
SS 316-4 |
10.000-14.000 |
10.123 |
16.000-18.000 |
16.543 |
|
SS 316-5 |
10.000-14.000 |
10.120 |
16.000-18.000 |
16.677 |
|
SS 316-6 |
10.000-14.000 |
10.136 |
16.000-18.000 |
16.729 |
|
SS 316-7 |
10.000-14.000 |
10.244 |
16.000-18.000 |
16.726 |
|
Number |
7 |
7 |
||
|
Maximum |
10.244 |
16.773 |
||
|
Minimum |
10.120 |
16.543 |
||
|
Range |
0.124 |
0.230 |
||
|
Average |
10.166 |
16.671 |
||
|
Standard deviation |
0.0535 |
0.0789 |
||
|
RSD% |
0.5262 |
0.4734 |
Table 1
Tags: XRF, Primus, WDXRF, alloys, semi-quantitative analysis