How Is Sulfur Analysis Performed?
Total sulfur by benchtop XRF or process XRT/XRA
The need for sulfur analysis permeates almost every aspect of the petroleum industry, from upgrading and refining through to transportation and retail. Rigaku offers X-ray based analytical solutions for all of the typical sulfur applications.
Sulfur in distillates, diesel, heavies, crude and marine fuel
The Rigaku NEX QC II Series benchtop EDXRF analyzers support compliance with ASTM D4294 for sulfur analysis, as well as ISO 20847, ISO 8754, IP 496, IP 336, and JIS K 2541-4, in a robust package designed for the petroleum industry. Optimized for routine determination of sulfur in petroleum, including crudes, heavies, and bunker fuel, as well as for upgrading operations, the NEX QC II Series features a clear, icon-driven touchscreen interface, an embedded computer, and a built-in thermal printer for convenient, self-contained operation.
For process gauging, the Rigaku NEX XT X-ray transmission (XRT) analyzer provides real-time sulfur determination. On-line measurement of sulfur in heavy and light oils supports the needs of refineries, pipelines, blending operations, bunkering terminals, and other storage facilities.
Ultra low sulfur in road diesel (ULSD) and other fuels
Designed for ultra-low level sulfur analysis of diesel, petrol (gasoline) and other fuels, the Rigaku Micro-Z ULS wavelength dispersive X-ray fluorescence (WDXRF) instrument features a novel design that measures both the sulfur peak and the back-ground intensity. The ability to measure and correct for changes in background intensity delivers a better net peak intensity measurement, resulting in superior calibrations and enhanced real world precision. Rigaku Micro-Z ULS complies with ASTM 2622-10, ISO 20884 and JIS K2541-7 methods.
The Rigaku NEX QC II+ benchtop EDXRF instrument delivers compliance with the ISO 13032 sulfur method for ULSD, and the high-performance Rigaku NEX CG II benchtop EDXRF is compliant with the ASTM D7220 method for ULSD.
Analyze sulfur plus other elements from Na through U
All Rigaku EDXRF analyzers have inherent multi-element analysis capability, supporting measurement of more than sulfur alone. In petroleum applications, multi-element analysis can help identify crude oil contamination or adulteration through the presence of salt and other chlorine-bearing compounds. If left undetected, chlorine can bias sulfur results high and potentially go unnoticed. Rigaku EDXRF analyzers can measure chlorine and other elements, providing additional elemental information alongside routine sulfur analysis.
Rigaku recommends the following products
ZSX Primus IV𝒾
High-power, tube-below, sequential WDXRF spectrometer with new ZSX Guidance expert system software
Learn moreSupermini200
Benchtop tube below sequential WDXRF spectrometer analyzes O through U in solids, liquids and powders
Learn moreNEX CG II Series
High-performance indirect excitation EDXRF for complex applications with trace elements and variable base matrices
Learn moreNEX DE Series
High-power 60 kV EDXRF systems delivering speed, precision, and small spot measurements
Learn moreApplication notes
The following application notes are relevant to this technique
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XRT1059 - Online Sulfur in Heavy Oils
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WDXRF1108 - Sulfur Analysis in Crude Oil and High-sulfur Fuels by WDXRF according to ASTM D2622-16
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WDXRF1107 - Analysis of Low-concentration Sulfur in Petroleum-based Fuels by WDXRF According to ASTM D2622-16
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WDXRF1106 - Sulfur Analysis in Petroleum Products by WDXRF according to ASTM D2622-16
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WDXRF1083 - Analysis of Ultralow Sulfur in Automotive Fuels According to ASTM D2622-16 by Micro-Z ULS
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WDXRF1082 - Sulfur Analysis in Crude Oil and high-sulfur Fuels by Benchtop WDXRF according to ASTM D2622-16
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WDXRF1081 - Analysis of Low-concentration Sulfur in Petroleum-based Fuels by Benchtop WDXRF according to ASTM D2622-16
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WDXRF1080 - Sulfur Analysis in Petroleum Products by Benchtop WDXRF According to ASTM D2622-16
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WDXRF1077 - Sulfur Analysis in Crude Oil and High-sulfur Fuels by WDXRF according to ASTM D2622-16
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WDXRF1076 - Analysis of Low-concentration Sulfur in Petroleum-based Fuels per ASTM D2622-16
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EDXRF3279 - NEX QC II - Sulfur in Oil by ASTM D4294
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EDXRF3272 - NEX QC II+ - Analysis of Lube Oils by ASTM D7751
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EDXRF2095 - Analysis of ULSD
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EDXRF2039 - NEX QC+—Cl and S in Waste Oil and Used Oil
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EDXRF1658 - NEX DE—Analysis of ULSD
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EDXRF1507 - NEX QC+—Activated Carbon
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EDXRF1331 - NEX QC+—Sulfur and Chlorine in Crude
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EDXRF1323 - NEX QC+—Analysis of S, V, Ni in Crude Oil
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EDXRF1312 - NEX QC+—Analysis of Lube Oils
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EDXRF1272 - NEX QC+—Analysis of ULSD and Gasoline
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EDXRF1249 - NEX QC—Analysis of Lube Oils per ASTM D6481
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EDXRF1231 - NEX QC—Sulfur in Coal
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EDXRF1230 - NEX QC—Sulfur in Bunker Fuel
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EDXRF1149 - NEX QC—Sulfur in Crude
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EDXRF1135 - NEX QC—Analysis of Sulfur in Diesel Fuel per ASTM D4294
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