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Rigaku Journal (ISSN 2187-9974)

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Winter 2020, Volume 36, No. 1

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Winter 2020, Vol.36, No.1

Characterization of lithium-ion battery materials with SmartLab

Yuji Shiramata and Takayuki Konya

Because lithium-ion batteries have higher energy density than other secondary batteries, it has been possible to make them smaller and lighter. This has enabled them to spread rapidly as power sources for mobile devices such as laptop computers and cellular phones. The demand for lithium-ion batteries keeps growing relentlessly and...

PDF analysis using X-ray total scattering —Theory and application examples

Masatsugu Yoshimoto and Yuji Shiramata

In recent years, pair distribution function (PDF) analysis has been used to characterize material structure in a wide research field. H. Kim reported the reduction mechanism in the reversible hydrogen storage capacity of V1-xTix alloys. B. Li et al., reported the mechanisms of the thermoelectric effect and...

Cement analysis by X-ray diffractometry

Atsushi Ohbuchi and Takahiro Kuzumaki

Cement is used as a raw material in the construction of buildings, tunnels, dams, and bridges. Basically, cement consists of clinker, calcium sulfate hydrate as a plaster component, aggregate, and water. The four major components of cement have different characteristics of time for hardening and strengthening of the cement; for...

Evaluation of MEMS device materials by X-ray fluorescence spectrometers for thin films

Yu Aoki

In the manufacturing process of semiconductor products, thin film inspection methods vary depending on the purpose. For example, optical such as ellipsometers, sheet resistance film thickness meters, step meters, and cross-sectional scanning electron microscopes (SEM) are used for film thickness management. For analysis of composition, X-ray photoelectron spectroscopy (XPS) or...

Application of the nano3DX X-ray microscope to biological specimens

Naoki Kunishima

Structural biology aims to understand life from observation of relevant biological structures and then to extend that knowledge to advance medicine, pharmaceutical development and so on. Because biological systems generally have hierarchical structures, the observation of biological systems varies in size range whether one is looking at tissue level structures...

Thermomechanical analyzer with refrigerated cooling unit - Thermo plus EVO2 TMA8311/LR

In recent years, there has been an increasing demand for non-liquid nitrogen based cooling systems in thermal analysis because of environmental considerations and usability. Especially in differential scanning calorimetry (DSC), refrigerated cooling unit is often used. Using the Rigaku DSC, low temperature measurements from −90°C can be carried out. This...

Summer 2019, Volume 35, No. 2

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Summer 2019, Volume 35, No. 2

Quantitative texture analysis in the Texture plugin of SmartLab Studio II

Keigo Nagao and Akito Sasaki

The presence of crystallographic texture (preferred orientation) in polycrystalline materials has a significant effect on the anisotropy of the properties of these materials. That means that quantitative description of the orientation distribution of crystallites, or the orientation distribution function (ODF), is an important task for materials characterization and prediction of...

Advanced ZSX Guidance—Semi-quantitative analysis (SQX analysis)

Yasujiro Yamada

Wavelength dispersive X-ray fluorescence (XRF) spectrometers have high spectral resolution and can therefore identify peaks with high accuracy. However, if the analysis line overlaps with a higher order line, peak identification and semi-quantitative analysis results may not be reliable. To perform accurate analysis for such cases, measurement conditions that reduce...

Determination of refractory products with the XRF quantitative application package

Wataru Matsuda and Takao Moriyama

Refractory products are materials that can withstand high temperatures, above 1500°C. They are used in a wide range of applications, including as the lining of furnaces that perform melting and heating processing of materials for metallurgical, chemical, ceramic, machine, glass industries and so on. There are many types of refractories...

Examination of electronic components with the nano3DX X-ray CT microscope

Yoshihiro Takeda

X-ray computed tomography (CT) is a nondestructive imaging technique that can be used to examine the internal features of an object in three dimensions (3D). The first commercial X-ray CT scanner was introduced 45 years ago and the technique has been widely used in the medical and industrial fields since...

Identification of hazardous compounds and illicit drugs with the handheld Raman spectrometers

Taro Nogami

Raman spectrometry is becoming a common method for identification of hazardous compounds and illicit drugs. Historically, infrared absorption spectroscopy was the common method, but the mainstream has gradually shifted to Raman spectroscopy. In particular, Raman spectrometry has a couple of advantages over infrared spectrometry for onsite rapid analysis. First, handheld...

Basic principle and operation methods of the direct-derivation method

Hideo Toraya

Quantitative phase analysis (QPA) using the X-ray diffraction technique is routinely employed to find weight ratios of individual component phases in a mixture. Techniques for QPA have been widely used not only in research and development but also routinely deployed for quality control of industrial products. Various techniques have been...